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Partial Pressure Calculator – Dalton’s Law, Mole Fraction & Gas Mixtures

⚗ Chemistry Calculator

Partial Pressure Calculator

This partial pressure calculator finds partial pressure using Dalton's Law, mole fractions, and the ideal gas law. Learn how to find partial pressure for gas mixtures with multiple components — results shown instantly in atm, kPa, mmHg, bar, and all common pressure units.

Dalton's Law — Total Pressure Calculator
Ptotal = P1 + P2 + P3 + … + Pn
Add the partial pressure of each gas component to find the total pressure

Enter the name and partial pressure of each gas. All pressures are converted to the same unit before summing.

χ Partial Pressure from Mole Fraction — PA = χA × Ptotal
PA = χA × Ptotal = (nA / ntotal) × Ptotal
Mole fraction χ is dimensionless — always between 0 and 1
🌡 Partial Pressure from Ideal Gas Law — PA = nART/V
PA = nA × R × T / V
R = 0.082057 L·atm/(mol·K)  |  Temperature must be in Kelvin
🧪 Gas Mixture Partial Pressure Calculator

Enter each gas component. Common gas molar masses are auto-filled when you type the gas name (e.g. "O2", "N2", "CO2"). PA = χA × Ptotal

What is Partial Pressure? — Dalton's Law of Partial Pressures

Partial pressure is the pressure that a single gas in a mixture would exert if it alone occupied the entire volume of the container at the same temperature. It represents that individual gas's contribution to the total pressure of the mixture. John Dalton formulated his Law of Partial Pressures in 1801: the total pressure of a gas mixture is the sum of the partial pressures of all component gases.

Ptotal = P1 + P2 + P3 + … + Pn
Dalton's Law of Partial Pressures
Pi = χi × Ptotal
Mole fraction χi = ni / ntotal  (dimensionless, always between 0 and 1, sum of all = 1)

This law assumes ideal gas behaviour — gas molecules do not interact with one another and occupy negligible volume themselves. In practice it is highly accurate for most gases under ordinary conditions.

Real-World Example: Atmospheric Air at Sea Level

  • N2 contributes ~78% → PN2 ≈ 0.7808 atm
  • O2 contributes ~21% → PO2 ≈ 0.2095 atm
  • Ar contributes ~1% → PAr ≈ 0.00934 atm
  • Ptotal = 0.7808 + 0.2095 + 0.00934 ≈ 1.000 atm ✓

Applications of Dalton's Law

  • Scuba diving: partial pressure of O2 and N2 increase with depth; narcosis and oxygen toxicity depend on their partial pressures.
  • Respiratory physiology: partial pressure of O2 in alveoli drives gas exchange across the lung membrane.
  • Industrial gas: storage and handling of gas mixtures require calculating individual partial pressures for safety limits.
  • Anesthesiology: anesthetic gases exert their effect proportional to their partial pressure in the blood.

Partial Pressure Formula — Mole Fraction Method

The mole fraction method is the most common way to calculate partial pressure in chemistry. It directly connects the amount of each gas to the pressure it exerts. PA = χA × Ptotal

χA = nA / ntotal
Mole fraction of gas A — dimensionless, between 0 and 1
PA = χA × Ptotal
Partial pressure from mole fraction
PA = (nA / ntotal) × Ptotal
Combined formula — substituting mole fraction definition

Key properties of mole fraction: it is dimensionless (no units), always between 0 and 1, and the sum of all mole fractions in a mixture exactly equals 1: Σχi = 1. For ideal gases at the same T and P, mole fraction equals volume fraction and pressure fraction. Mole% = χ × 100%.

Example — Dry air: N2 mole fraction = 0.7809 = 78.09 mol%. At 1 atm: PN2 = χN2 × Ptotal = 0.7809 × 1 atm = 0.7809 atm = 79.12 kPa.

How to Find Partial Pressure — Step by Step

There are three main methods for how to find partial pressure. The correct method depends on what information you are given.

Method 1: From Known Partial Pressures (Dalton's Law) — Ptotal = P1 + P2 + P3

  1. List all partial pressures in the same units.
  2. Add them: Ptotal = P1 + P2 + … + Pn.
  3. Unknown partial pressure = Ptotal − (sum of all known partial pressures).

Method 2: From Moles and Total Pressure

  1. Find moles of each gas.
  2. ntotal = Σni.
  3. χA = nA / ntotal.
  4. PA = χA × Ptotal.

Method 3: From Ideal Gas Law

  1. Note nA (mol), V (L), T (K).
  2. PA = nA × R × T / V.
  3. Use R = 0.082057 L·atm/(mol·K).

Worked Example — Air Composition: 3.12 mol N2, 0.84 mol O2, 0.04 mol Ar, Ptotal = 4.00 atm

  1. ntotal = 3.12 + 0.84 + 0.04 = 4.00 mol
  2. χN2 = 3.12 / 4.00 = 0.780 → PN2 = 0.780 × 4.00 = 3.120 atm
  3. χO2 = 0.84 / 4.00 = 0.210 → PO2 = 0.210 × 4.00 = 0.840 atm
  4. χAr = 0.04 / 4.00 = 0.010 → PAr = 0.010 × 4.00 = 0.040 atm
  5. Check: 3.120 + 0.840 + 0.040 = 4.000 atm ✓  |  χ sum: 0.780 + 0.210 + 0.010 = 1.000 ✓

How to Calculate Partial Pressure from Moles

When you know the mass or moles of each gas and the total pressure, use this four-step method to calculate partial pressure from moles. This is the most common exam scenario.

  1. Step 1: Convert grams to moles if needed: n = mass(g) ÷ molar mass(g/mol)
  2. Step 2: Sum all moles: ntotal = Σni
  3. Step 3: Calculate mole fraction: χA = nA / ntotal
  4. Step 4: Partial pressure: PA = χA × Ptotal

Example 1: 14 g N2 and 16 g O2, Ptotal = 2.00 atm

  1. nN2 = 14 ÷ 28.014 = 0.4998 mol
  2. nO2 = 16 ÷ 31.998 = 0.5000 mol
  3. ntotal = 0.4998 + 0.5000 = 0.9998 mol
  4. χN2 = 0.4998 / 0.9998 = 0.4999 → PN2 = 0.4999 × 2.00 = 1.000 atm
  5. χO2 = 0.5000 / 0.9998 = 0.5001 → PO2 = 0.5001 × 2.00 = 1.000 atm

Example 2: 0.5 mol H2, 0.3 mol He, 0.2 mol Ar, Ptotal = 5.00 atm

  1. ntotal = 0.5 + 0.3 + 0.2 = 1.00 mol
  2. χH2 = 0.50 → PH2 = 0.50 × 5.00 = 2.50 atm
  3. χHe = 0.30 → PHe = 0.30 × 5.00 = 1.50 atm
  4. χAr = 0.20 → PAr = 0.20 × 5.00 = 1.00 atm

Example 3: Partial Pressure of Nitrogen in Dry Air at Sea Level

  1. Dry air: 78.09% N2 by mole → χN2 = 0.7809
  2. Ptotal = 101.325 kPa (1 atm)
  3. PN2 = χN2 × Ptotal = 0.7809 × 101.325 = 79.12 kPa = 0.7809 atm

Pressure Unit Conversion Table

Standard atmospheric pressure: 1 atm = 101.325 kPa = 760 mmHg = 1.01325 bar = 14.696 psi = 101,325 Pa

Unit= atm= kPa= mmHg= bar= Pa= psi
1 atm1101.3257601.01325101,32514.696
1 kPa0.00986917.50060.011,0000.14504
1 mmHg (torr)0.0013160.1333210.001333133.320.01934
1 bar0.98692100750.061100,00014.504
1 Pa9.869×10?60.0010.00750.0000110.000145
1 psi0.0680466.894851.7150.0689486,894.81

Partial Pressure of Gases in Dry Air at Sea Level

At standard sea-level pressure (1 atm = 101.325 kPa = 760 mmHg), the partial pressures of the main atmospheric gases are:

GasMole Fraction (χ)P (atm)P (kPa)P (mmHg)
Nitrogen (N2)0.780840.7808 atm79.12 kPa593.4 mmHg
Oxygen (O2)0.209460.2095 atm21.22 kPa159.2 mmHg
Argon (Ar)0.009340.00934 atm0.946 kPa7.10 mmHg
Carbon dioxide (CO2)0.0004210.000421 atm0.0427 kPa0.320 mmHg
Total (dry air)1.000001.0000 atm101.325 kPa760.0 mmHg

Note: partial pressure of oxygen in the alveoli of the lungs is lower (~13.3 kPa) due to dilution by water vapour (~6.3 kPa) and CO2 (~5.3 kPa) in the alveolar air. Partial pressure of nitrogen at sea level: PN2 = 0.7808 atm = 79.12 kPa = 593.4 mmHg.

Worked Examples

1. Finding Partial Pressure Using Dalton's Law (Ptotal = P1 + P2 + P3)

Three gases are in a container: PN2 = 0.78 atm, PO2 = 0.21 atm, PAr = 0.01 atm. By Dalton's Law, Ptotal = PN2 + PO2 + PAr = 0.78 + 0.21 + 0.01 = 1.00 atm. To find an unknown partial pressure, rearrange: Punknown = Ptotal − (sum of known pressures).

2. Partial Pressure from Mole Fraction — PA = χA × Ptotal

A gas mixture has Ptotal = 3.00 atm. Gas A has χA = 0.40. Apply the formula: PA = χA × Ptotal = 0.40 × 3.00 = 1.20 atm = 121.6 kPa. Verify: if χB = 0.60, then PB = 0.60 × 3.00 = 1.80 atm; 1.20 + 1.80 = 3.00 atm ✓.

3. Partial Pressure from Moles and Total Pressure

3 mol N2 and 1 mol O2 at Ptotal = 4 atm. ntotal = 4 mol. χN2 = 3/4 = 0.75 → PN2 = 0.75 × 4 = 3.00 atm. χO2 = 1/4 = 0.25 → PO2 = 0.25 × 4 = 1.00 atm. Check: 3.00 + 1.00 = 4.00 ✓.

4. Finding Total Pressure from Partial Pressures

Given PH2 = 250 mmHg, PHe = 375 mmHg, PAr = 135 mmHg. Convert to same unit (already in mmHg). Ptotal = P1 + P2 + P3 = 250 + 375 + 135 = 760 mmHg = 1.00 atm. Dalton's Law requires all pressures in the same unit before summing.

5. Partial Pressure Using the Ideal Gas Law — PA = nART/V

n = 0.5 mol O2, V = 10 L, T = 25°C = 298.15 K. PO2 = (0.5 × 0.082057 × 298.15) / 10 = 12.232 / 10 = 1.223 atm = 123.9 kPa. Always convert °C to K by adding 273.15 before using PV = nRT.

6. Partial Pressure of Oxygen in Air

Oxygen makes up 20.946% of dry air by mole. χO2 = 0.20946. At Ptotal = 1 atm: PO2 = χO2 × Ptotal = 0.20946 × 1 = 0.2095 atm = 21.22 kPa = 159.2 mmHg. In the lungs this drops to ~13.3 kPa due to water vapour and CO2.

7. Partial Pressure of Nitrogen at Sea Level

N2 mole fraction in dry air = 0.78084. At 1 atm: PN2 = 0.78084 × 1 atm = 0.7808 atm = 0.7808 × 101.325 = 79.12 kPa = 0.7808 × 760 = 593.4 mmHg. This is the partial pressure of nitrogen that causes nitrogen narcosis in scuba diving at depth.

8. Partial Pressure from Grams of Each Gas

32 g O2 and 28 g N2 in a container at Ptotal = 3 atm. nO2 = 32/31.998 = 1.000 mol; nN2 = 28/28.014 = 0.9995 mol; ntotal = 1.9995 mol. χO2 = 1.000/1.9995 = 0.5001; PO2 = 0.5001 × 3 = 1.500 atm. χN2 = 0.4999; PN2 = 0.4999 × 3 = 1.500 atm.

9. Mole Fraction from Partial Pressure

If Ptotal = 5.00 atm and PCO2 = 0.75 atm, find χCO2. Rearrange PA = χA × Ptotal: χCO2 = PCO2 / Ptotal = 0.75 / 5.00 = 0.150 = 15.0 mol%. This confirms that mole fraction = pressure fraction for ideal gases.

10. Partial Pressure in a Three-Component Gas Mixture

2 mol CH4, 1 mol CO2, 0.5 mol H2, Ptotal = 7.00 atm. ntotal = 3.5 mol. χCH4 = 2/3.5 = 0.5714 → PCH4 = 0.5714 × 7 = 4.000 atm. χCO2 = 1/3.5 = 0.2857 → PCO2 = 2.000 atm. χH2 = 0.5/3.5 = 0.1429 → PH2 = 1.000 atm. Sum: 4+2+1 = 7.00 ✓.

Frequently Asked Questions

What is partial pressure?
Partial pressure is the pressure a single gas in a mixture would exert if it alone occupied the entire container volume at the same temperature. It represents that gas's individual contribution to the total mixture pressure. Calculated as Pi = χi × Ptotal.
What is Dalton's Law of Partial Pressures?
Dalton's Law states that the total pressure of a gas mixture equals the sum of all partial pressures: Ptotal = P1 + P2 + P3 + … + Pn. Formulated by John Dalton in 1801, it assumes ideal gas behaviour with no interactions between molecules.
How do you calculate partial pressure from mole fraction?
Use the formula PA = χA × Ptotal. First find the mole fraction: χA = nA / ntotal. Multiply by the total pressure of the mixture. Example: χO2 = 0.21, Ptotal = 1 atm → PO2 = 0.21 × 1 = 0.21 atm.
How do you find total pressure from partial pressures?
Add all partial pressures in the same unit: Ptotal = P1 + P2 + P3 + …. Convert to a common unit first if needed. Example: PN2 + PO2 + PAr = 0.78 + 0.21 + 0.01 = 1.00 atm.
What is the formula for partial pressure?
Three formulas: (1) Dalton's Law: Ptotal = P1 + P2 + …; (2) Mole fraction: PA = χA × Ptotal where χA = nA/ntotal; (3) Ideal gas law: PA = nART/V with R = 0.082057 L·atm/(mol·K).
How do you find partial pressure from moles?
(1) Sum all moles: ntotal. (2) Find χA = nA/ntotal. (3) Multiply: PA = χA × Ptotal. If you have grams instead of moles, convert first: n = mass ÷ molar mass.
What is the partial pressure of oxygen in air?
In dry air at sea level: PO2 = 0.2095 atm = 21.22 kPa = 159.2 mmHg. Calculated from χO2 = 0.20946 and Ptotal = 1 atm. In the lungs, it drops to ~13.3 kPa due to water vapour and CO2 dilution.
How does partial pressure relate to the ideal gas law?
Each gas in a mixture individually obeys PV = nRT: PAV = nART, so PA = nART/V. The total pressure is the sum of all individual gas pressures, consistent with Dalton's Law. This connection means mole fraction equals pressure fraction for ideal gases.
What are the units of partial pressure?
Same as total pressure: atm, kPa, Pa, mmHg (torr), bar, or psi. Standard conversion: 1 atm = 101.325 kPa = 760 mmHg = 1.01325 bar = 14.696 psi = 101,325 Pa.
How do you convert between pressure units?
Convert to atm first, then to target unit. Key factors: divide mmHg by 760 to get atm; divide kPa by 101.325 for atm; divide bar by 1.01325 for atm. Then multiply atm by the target factor (e.g., ×101.325 for kPa, ×760 for mmHg).

Related Calculators

📐 Key Formulas
1
Dalton's Law: Ptotal = P1 + P2 + P3 + …
2
Mole Fraction: PA = χA × Ptotal
3
Ideal Gas: PA = nART/V
4
Mole fraction: χA = nA/ntotal
5
Σχ = 1 always — mole fractions sum to exactly 1
💡 Quick Conversions
1 atm = 101.325 kPa
1 atm = 760 mmHg
1 atm = 1.01325 bar
1 atm = 14.696 psi
1 atm = 101,325 Pa
🔬 Gas Molar Masses
N228.014 g/mol
O231.998 g/mol
CO244.009 g/mol
H22.016 g/mol
He4.003 g/mol
Ar39.948 g/mol
CH416.043 g/mol
NH317.031 g/mol
📊 Air Composition
N2
χ = 0.7808 → 79.12 kPa
O2
χ = 0.2095 → 21.22 kPa
Ar
χ = 0.00934 → 0.946 kPa
CO2
χ = 0.000421 → 0.043 kPa

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